Name No bonding pairs No lone pairs Diagram Bond angle Examples linear 2 0 180 CO2, CS2 , HCN, BeF2 Trigonal planar 3 0 120 BF3 , AlCl3 , SO3 , NO3 -, CO3 2- Tetrahedral 4 0 109.5 SiCl4 , SO4 2-, ClO4 -, NH4+ Trigonal pyramidal 3 1 107 NCl3 ,PF3 ,ClO3 ,H3O+ Bent 2 2 104.5 OCl2 , H2S, OF2 , SCl2 Octahedral 6 0 90 SF6 S. Shape of molecules. How to explain shape 1. State number of bonding pairs and lone pairs of electrons. 2. State that electron pairs repel and try to get as far apart as possible (or to a position of minimum repulsion.) 3. If there are no lone pairs state that the electron pairs repel equally 4. If there are lone pairs of electrons, then state that lone pairs repel more than bonding pairs. 5. State actual shape and bond angle. Remember lone pairs repel more than bonding pairs and so reduce bond angles (by about 2.5o per lone pair in above examples)
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2.2.2 Bonding and structure
The shapes of simple molecules and ions (g) the shapes of, and bond angles in, molecules and ions with up to six electron pairs (including lone pairs) surrounding the central atom as predicted by electron pair repulsion, including the relative repulsive strengths of bonded pairs and lone pairs of electrons M4.1, M4.2 Learners should be able to draw 3-D diagrams to illustrate shapes of molecules and ions. HSW1,2 Using electron pair repulsion theory to predict molecular shapes. (h) electron pair repulsion to explain the following shapes of molecules and ions: linear, non-linear, trigonal planar, pyramidal, tetrahedral and octahedral Learners are expected to know that lone pairs repel more than bonded pairs and the bond angles for common examples of each shape including CH4 (109.5°), NH3 (107°) and H2O (104.5°).