CIE Jun 2017 v3 Paper 5 Q2

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Sucrose is a sugar. The concentration of a solution of sucrose can be measured by the optical rotation, , of a sucrose solution. The more concentrated the solution, the greater the optical rotation of the solution. PMT A polarimeter is used to measure optical rotation. Light is passed through a sample of the sucrose solution in a glass cell, and the observed angle of rotation, obs, is measured. A simplified diagram of a polarimeter is shown. eyepiece eye of observer light glass cell rotated light If a glass cell of length 10 cm is filled with a solution of sucrose of concentration 1 g cm3 the measured angle of rotation is known as the specific rotation, []. The observed angle of rotation, obs, measured by the polarimeter is related mathematically to the concentration of the sucrose solution by the equation shown. obs = []c obs is the observed angle of rotation using a 10 cm cell [] is the specific rotation of sucrose solution c is the concentration of sucrose, in g cm3 A student wanted to determine the specific rotation of sucrose, []. Solutions of different concentrations of sucrose at 20 C were placed in a polarimeter and the observed angle of rotation, obs, recorded. The + sign is used to show that the rotation is in a clockwise direction.UCLES 2017 9701/53/M/J/17 [Turn over<br /> PMT observed angle of rotation, obs +5.05 +4.70 +4.40 +4.00 +3.30 +2.55 +2.30 +1.95 +1.68 +1.40 concentration of sucrose, c / g cm3 0.0750 0.0700 0.0650 0.0600 0.0500 0.0450 0.0350 0.0300 0.0250 0.0200 (a) (i) Plot a graph on the grid on page 9 to show the relationship between concentration of sucrose, c, and observed angle of rotation, obs. Use a cross () to plot each data point. Draw a line of best fit. [2] (ii) (iii) Circle the most anomalous point on your graph. [1] Use the graph to determine the specific rotation, [], of sucrose. Give this value to two decimal places. State the co-ordinates of both points you used in your calculation. co-ordinates 1co-ordinates 2specific rotation of sucrose, [] =[2]UCLES 2017 9701/53/M/J/17<br /> PMT 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 obs 0.0 0.000 0.0100 0.0200 0.0300 0.0400 0.0500 0.0600 0.0700 0.0800 c / g cm3UCLES 2017 9701/53/M/J/17 [Turn over<br /> 10 (b) You are asked to write instructions for another student to follow so they can prepare a standard solution of 250 cm3 0.0750 g cm3 sucrose. The student is provided with solid sucrose and a 250 cm3 volumetric flask. (i) Calculate the mass, in g, of sucrose the student would need to use. PMT (ii) Describe how the student should accurately prepare the standard solution using a sample of sucrose of mass calculated in (i). mass of sucrose =g [1][2] (c) (i) The student used the standard solution prepared in (b) to prepare the solutions in the table on page 8. Calculate the volume of standard solution of concentration 0.0750 g cm3 and the volume of distilled water needed to prepare 15.00 cm3 of sucrose solution of concentration 0.0350 g cm3. Give your answers to two decimal places. volume of standard solution =cm3 volume of distilled water =cm3 [1]UCLES 2017 9701/53/M/J/17<br /> PMT 11 The volumes of the two solutions given in (c)(i) could be measured using the same type of apparatus. (ii) Name a suitable piece of apparatus which could be used to measure these volumes.[1] (iii) In (a)(ii) you circled an anomalous point. This was caused by the student incorrectly making one of the sucrose solutions. Suggest the error made by the student that caused this anomaly.[1] (d) The student recorded the observed angle of rotation, obs, for a sucrose solution of unknown concentration as +3.75. Determine the concentration of this sucrose solution in mol dm3. [Mr sucrose: 342] concentration of sucrose =mol dm3 [3]UCLES 2017 9701/53/M/J/17 [Turn over<br /> PMT 12 (e) The glass cell of 10 cm length is expensive, so one cell is used for all the solutions that are placed in the polarimeter. Suggest how you would ensure that the concentration of solution in the cell is accurate each time the cell is used for the different sucrose solutions.[1] (f) Concentration of sucrose is the independent variable in this polarimeter experiment. The glass cell of 10 cm length is replaced by a glass cell of 20 cm length. The 20 cm glass cell is filled with 0.0750 g cm3 sucrose solution. Predict the value for the observed angle of rotation, obs, for the sucrose solution of concentration 0.0750 g cm3 when the 20 cm cell is used. Explain your answer. predicted value =explanation[2] (g) Before the angles of rotation of the sucrose solutions are measured, the glass cell is first filled with distilled water and the angle of rotation measured. Explain why this measurement is taken.[1] [Total: 18] Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after the live examination series. Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.UCLES 2017 9701/53/M/J/17<br />

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